I am puzzled at how many questions pop up on the Quora question and answer site about electron orbits in atoms. According to basic physics such orbits cannot exit, but apparently we are still teaching students that they do, in fact we are indoctrinating them with this sacred knowledge. I remember seeing a grade school “science” project in which students dyed some cotton balls various colors and then glued them to a piece of paper with concentric circles drawn upon them. Nothing, absolutely nothing, about this exercise is correct. But it does inculcate the idea in little minds that electrons (whatever they are) orbit around a nucleus, whatever it is.
There are so many mistakes, bad assumptions, etc. made in the development of early atom models it is no wonder that the quantum theory of the atom, what the quantum theory in general is based upon, is completely not understandable.
Allow me to step you though the development of these theories. Here are the years of discovery of the main characters:
electron—1897
proton—1919
neutron—1932.
The electron was discovered through a intense investigation of radioactivity. Radioactive substances were shown to emit three types of radiation (things that radiate outward from a point): alpha, beta, and gamma radiations. Obviously they knew little of what these things were because they labeled them a, b, and c (in Greek, of course). Alpha radiation turned out to be streams of positively charged helium atoms, gamma radiation tuned out to be a form of electromagnetic radiation, and beta rays turned out to be streams of electrons. The masses of the beta particles was so small that they had to be smaller than the smallest atom (at least lighter). This created an attention storm because the electron was the first “subatomic” particle ever characterized. By subatomic it was meant, less than the size/mass of an atom. Prior to that point it was assumed that atoms were “uncuttable” (what the word atom means in Greek) and that nothing smaller could exist. Very quickly, with no evidence provided, it was conjectured that the electrons were component particles of atoms. When we finally deduced the mechanism of the emission of beta radiation we found out that the electrons were created in the process and not part of the atom prior to that point. So, electrons were not a part of the atom, at least when it came to beta decay radioactivity. But. atom models containing electrons were immediately floated. Just like today’s news organizations, everyone wanted to be first rather than correct. When the proton was discovered, in 1919 (its charge-to-mass ratio was measured in 1898 indicting it had a very high mass) once again it was “discovered” based upon a radioactive process in which protons were emitted. Again, there was no reason to assume the protons existed prior to the radioactive event, but what the heck.
In 1911 Rutherford and his assistants did the now famous gold foil experiments in which alpha particles were “fired” against super thin foils of metals (not just gold) and most went through but a tiny, tiny fraction were deflected. And even more rarely some alpha particles bounced backward. From this Rutherford concluded that all of the mass of the atoms was concentrated in a very small central core, which he called a nucleus, and that core had to be positive because the positive alpha particles bounced off rather than stuck to the gold “nuclei.” Apparently the 197 to 4 weight difference between gold atoms and alpha particles was not enough explanation for why the alpha particles bounced off. And why did anyone assume the alpha particles would stick? And if the nuclei were positive, a negative component was also needed and voilà, the electrons were given a meaning for their little lives. This was also based upon the supposition, again not proven, that the atoms were touching. If the atoms were not touching, the nuclear idea was a nonstarter.
Immediately upon the “nucleus” being discovered (not) the planetary model of the atom was promoted. (Actually this model was invented years prior (in 1903) by Hantaro Nagaoka of Japan.) But the model met immediate opposition because electrons are significantly negatively charged for such a small particle and orbiting a positively charged nucleus would cause the electrons to lose energy (all charged particles undergoing acceleration in a charge field lose energy by emitting EMR—orbits involve a particle continuously changing direction and that requires a force and an acceleration because F = ma).
Bohr worked on this problem extensively and then announced a fix. His model has electrons in circular orbits, those orbits required electrons to have fixed energies, and therefore fixed orbit diameters which were said to be “quantized.”
Now the concept of the quantum of energy had been introduced in 1900 but that merely extended the idea that matter came in bits to electromagnetic energy coming in bits, too. Bohr’s model has the electrons being somehow fixed in certain “allowed” orbits. No reason for this “quantization” of atomic electron energies was ever offered. It just worked!
Now, as to “worked,” Bohr’s model “explained” why atomic emission spectra were how they were. Atomic emission spectra are the mix of various EMR “lights” given off when an element’s atoms are heated up enough to glow, or give off light. (The example you know of is “neon lighting.”) Those spectra, when spread out, showed that only a few colors of light were emitted. Bohr explain those colors as the energies of electrons as they transitioned from one orbit to another. So, no explanation was offered why the orbits energies were so constrained or how it was that electrons could “jump” from one orbit to another. But it worked they said. Closer inspection showed that the energies of the electron orbits in hydrogen were determined from those self-same lights of hydrogen’s emission spectrum so they damn well should have matched.
Bohr’s theory should have raised all kinds of alarms, but maybe there was so much going on that nobody bit. No explanation for the orbits being allowed at all. No explanation for the energies of the atomic electrons being restricted to certain quantities. And none of it was done to preserve some semblance of normal theory. It was all just pulled out of a hat.
While Bohr’s theory has been discredited, it is still taught in schools. It is taught for reasons I approve of and that is using intellectual history as a framework. Basically, this idea led to that one and that one lead to this new one and . . . which exposes people’s thinking as new data are made available. (It also exposes our propensity to get ahead of ourselves and make mistakes.) But it seems that many student’s educations didn’t involve getting to the point of the failure of Bohr’s atom model and the things that replaced it. Parts of Bohr’s atom model are included in today’s models, even though the thing proved to be wrong. So, Bohr’s quantized orbits are gone, only to be replaced by quantized orbitals (very poor terminology) with still no reason why there should be any restriction of what an electron’s energy might be. Taken out of atoms, electrons can be made to have any energy and even to sing and dance (well, maybe not the latter, but there is no restrictions upon what energies they might have).
And people still whine about how quantum theory math works but conceptually it is incoherent. Maybe if someone could come up with a physical mechanism by which atomic electron energies could be restricted, we might make some progress, but nobody s working on that. That is old hat! There is dark matter and dark energy to pursue!
There is an old saw about not confusing the edge of the rut you are in for the horizon. In this case we are not in a rut, but have gone down a rabbit hole.
Another Mass Shooting . . .
Tags: Americans and guns, Corporate Greed, corruption, killing children, mass shootings, Republicans
Three adults and three children died as the result of a mass shooting in Nashville, Tennessee. The school was a private Christian school and the shooter, unusually, was a woman.
So as ye sew, so shall ye reap. The woman was armed with two assault-style rifles, probably AR-15s, the preferred assault weapon of Christian fundamentalists. And I wouldn’t be surprised to find out that the woman was a member of the church sponsoring the school.
Maybe support for unfettered gun ownership will begin to sag in these circles, now that problems with such guns have come home to roost.